如题,急求过硫酸钠,杀菌剂,叔丁基过氧化氢的英文版MSDS,麻烦帮帮忙,

如题,急求过硫酸钠,杀菌剂,叔丁基过氧化氢的英文版MSDS,麻烦帮帮忙,
如题,急求过硫酸钠,杀菌剂,叔丁基过氧化氢的英文版MSDS,麻烦帮帮忙,

如题,急求过硫酸钠,杀菌剂,叔丁基过氧化氢的英文版MSDS,麻烦帮帮忙,
这是 叔丁基过氧化氢的
**** MATERIAL SAFETY DATA SHEET ****
tert-Butyl hydroperoxide, 70% solution in water.
**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****
MSDS Name: tert-Butyl hydroperoxide, 70% solution in water.
Catalog Numbers:
18034-0000, 18034-0050, 18034-2500, 18034-5000
Synonyms:
TBHP
Company Identification (Europe): Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
Company Identification (USA): Acros Organics
One Reagent Lane
Fairlawn, NJ 07410
For information in North America, call: 800-ACROS-01
For information in Europe, call: 0032(0) 14575211
For emergencies in the US, call CHEMTREC: 800-424-9300
For emergencies in Europe, call: 0032(0) 14575299
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
| CAS# | Chemical Name | % | EINECS# |Haz Symbols| Risk Phrases |
|----------------|--------------------------------------|----------|-----------|-----------|---------------+
|----------------|--------------------------------------|----------|-----------|-----------|---------------|
| 75-91-2 |tert-Butyl hydroperoxide | 70% | 200-915-7 | E C| 2 20/21/22 34 7|
|----------------|--------------------------------------|----------|-----------|-----------|---------------|
| 7732-18-5 |Water | | 231-791-2 |||
+----------------+--------------------------------------+----------+-----------+-----------+---------------+
Text for R-phrases: see Section 16
Hazard Symbols: O C
Risk Phrases: 10 20/21/22 34 43 7
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if
swallowed. Causes burns. May cause sensitization by skin contact.
May cause fire. Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye burns. May cause eye injury.
Skin:
Harmful if absorbed through the skin. Causes skin burns. May cause
sensitization by skin contact.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. May cause burning
sensation, coughing, wheezing, laryngitis, shortness of breath,
headache, nausea, and vomiting.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with combustible materials
may cause a fire. Will burn if involved in a fire.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use dry chemical,
carbon dioxide, or alcohol-resistant foam. Do NOT use halogenated
agents.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Remove all sources of ignition. Use
a spark-proof tool. Isolate area and deny entry. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Take precautionary measures against static discharges. Use
only in a chemical fume hood.
Storage:
Do not store near combustible materials. Store in a tightly closed
container. Store in a dry area. Refrigerator/flammables. Keep at
temperature not exceeding 45°C.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: APHA: 20 max
Odor: weak odor
pH: Not available.
Vapor Pressure: 62 mm Hg @ 45 deg C
Viscosity: 4.1 mPas 20 deg C
Boiling Point: 37 deg C @ 15 mmHg
Freezing/Melting Point: -2.8 deg C
Autoignition Temperature: 204 deg C ( 399.20 deg F)
Flash Point: 43 deg C ( 109.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 75 deg C
Solubility in water: Miscible.
Specific Gravity/Density: .9400g/cm3
Molecular Formula: C4H10O2
Molecular Weight: 90.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
A dangerous self-accelerating decomposition reaction and, under
certain circumstances, explosion or fire can be caused by direct
contact with incompatible substances or by thermal decomposition at
and above the SADT (see Section 16).
Conditions to Avoid:
Incompatible materials, light, ignition sources, combustible
materials, organic materials, temperatures above 75°C (167°F),
freezing temperatures.
Incompatibilities with Other Materials:
Reducing agents, acids, bases, finely powdered metals, heavy metals.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-91-2: EQ4900000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 75-91-2: Draize test, rabbit, eye: 7 mg; Draize test, rabbit,
eye: 100 mg/24H Moderate; Draize test, rabbit, eye: 70 uL Severe;
Draize test, rabbit, eye: 75%; Draize test, rabbit, eye: 0.02 mL;
Draize test, rabbit, skin: 500 mg; Draize test, rabbit, skin: 500
mg/24H Severe; Inhalation, mouse: LC50 = 350 ppm/4H; Inhalation,
mouse: LC50 = 1800 mg/m3/4H; Inhalation, rat: LC50 = 500 ppm/4H;
Inhalation, rat: LC50 = 1800 mg/m3/4H; Oral, mouse: LD50 = 320 mg/kg;
Oral, mouse: LD50 = 320 mg/kg; Oral, rat: LD50 = 370 mg/kg; Oral,
rat: LD50 = 370 mg/kg; Skin, rabbit: LD50 = 460 uL/kg; Skin, rat:
LD50 = 790 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Irritation:
Eye, rabbit: 7 mg
Eye, rabbit: 150 mg/1M severe
Carcinogenicity:
tert-Butyl hydroperoxide -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Water -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Zebrafish: LC50: 57 mg/l; 96H; acute
Other
Not readily biodegradable. Avoid entering into waters or underground
water.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ORGANIC PEROXIDE TYPE F, LIQUID*
Hazard Class: 5.2
UN Number: 3109
Packing Group:
IMO
Shipping Name: ORGANIC PEROXIDE TYPE F, LIQUID (tert-Butyl hydrop
eroxide)
Hazard Class: 5.2
UN Number: 3109
Packing Group:
RID/ADR
Shipping Name: ORGANIC PEROXIDE TYPE F, LIQUID (tert-Butyl hydrop
eroxide)
Hazard Class: 5.2
UN Number: 3109
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 34 Causes burns.
R 43 May cause sensitization by skin contact.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 7 May cause fire.
Safety Phrases:
S 3/7 Keep container tightly closed in a cool,
well-ventilated place.
S 14A Keep away from acids, reducing agents and
polymerisation catalysts.
S 16 Keep away from sources of ignition - No
smoking.
S 17 Keep away from combustible material.
S 24 Avoid contact with skin.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 75-91-2: No information available.
CAS# 7732-18-5: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 75-91-2 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 75-91-2 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 75-91-2: OEL-GERMANY
OEL-RUSSIA:STEL 5 mg/m3;Skin
US FEDERAL
TSCA
CAS# 75-91-2 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
SADT (Self-Accelerating Decomposition Temperature): 80°C
MSDS Creation Date: 10/28/1996 Revision #2 Date: 8/02/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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